WebInstead, charge carriers are localized at molecular entities, e.g. oligomers or segments of a conjugated polymer chain and move by incoherent hopping among adjacent sites with statistically variable energies. Quite often the site energies feature a Gaussian distribution. Also the hopping distances can vary statistically (positional disorder). WebThe interplane spin cross relaxation time Tx measured by high frequency ESR in X-ray irradiated κ-(BEDT-TTF)2Cu[N(CN)2]Cl is compared to the interplane resisitivity ρ⊥and the in-plane resistivity ρII between 50 K and 250 K. The irradiation transforms the semiconductor behavior of the non-irradiated crystal into metallic. Irradiation decreases Tx, ρ⊥ and ρII but …
Influence of Coherent Tunneling and Incoherent Hopping …
WebCoherent hopping of excitation relies on quantum coherence over physically extended states. In this work, we consider simple models to examine the effect of symmetries of delocalized multi-excitation states on the dynamical timescales, including hopping rates, radiative decay and environmental interactions. Webadjective. without logical or meaningful connection; disjointed; rambling: an incoherent sentence. characterized by such thought or language, as a person: incoherent with rage. … grammar for chrome
Coherent quantum transport in disordered systems: A unified …
WebJul 31, 2011 · Although it is widely accepted that such behaviour is a signature of a thermally assisted incoherent (hopping) mechanism, density functional theory calculations and an accompanying analytical... WebNov 3, 2024 · We show how the hopping process may create excitations when starting from a state with a finite excitation density. That is, how hopping can change the state of a lower polariton condensate by creating upper polaritons, optically inactive excitonic dark states, or by exciting vibrational sidebands. WebMar 16, 2024 · The presented free-energy description of energy transfer reveals that typical photosynthetic systems operate in an almost barrierless regime. The approach also provides insights into the distinction between coherent and incoherent energy transfer and the criteria by which the necessity of the vibrational assistance is considered. china railway express co. ltd